Just for laughs, try dropping the pressure in problem areas.
Here's what's happening:
You have a bunch of hot air trapped in the cyl, and it's getting hotter as a function of crank rotation.
You spray high-pressure liquid fuel into the air. As it vaporizes, it cools the air down around the fuel. Only fuel that is a "gas" can burn, liquids can't burn. There is no way for air molecules get past the surface of a fuel droplet.
Fuel will vaporize faster at higher pressures, because the droplet size is smaller, hence more surface area per mm3 of liquid fuel. However, the faster it vaporizes, the more the air gets cooled, AND the rate that the fuel is coming in at increases as well. Lower fuel pressure might make bigger droplets, but it also keeps the air temp up to allow for more combustion.
When you vaporize the fuel too fast, it can slow down the combustion. If it slows down to the point the liquid fuel hits the walls of the cylinders before it becomes a gas, it REALLY slows down combustion, and this is where most black smoke comes from. Fuel can barely burn when it's stuck on a surface, so it only burns partially.
Bumping the pressure up can either help the situation, or hurt the situation, depending on whether it's retarding combustion. Think about this for a second - Why does GM reduce fuel pressure at lower RPM's? Especially if higher pressure can yield better vaporization? Reason - They have to. They have no choice but wait for higher air temps in the cylinder before they can increase the pressure.
Now at WOT/Max Boost, get as much fuel pressure as possible. The air is brutally hot when you get a lot of boost going. But when you DON'T have boost, you probably can't run high pressure without spraying the walls with most of your fuel.
Large injectors aggravate the situation because by their nature, they make larger droplets.