You wont be able to retain 4-low with the push-button transfer case if you swap to a ZF6 OS, eliminate the TCM, and do it the "correct" way.
If you want to keep 4wd low with a push-button transfer case on a ZF6, you'll have to keep the TCM wired up, keep the Allison OS, with a dummy NSBU wired in so the transfer case control module will get a "neutral" flag from the TCM, allowing you to shift to 4wd low.
Easier/simpler/better to just swap to a ZF6 OS, and swap to manual transfer case.