What makes you think this stuff hasn't been tried, or is not currently done? The tables are there in EFILIVE to change the desired shift times. Also keep in mind, unless you have an 11+, your not palying with pressure per say, but you can adjust the theoretical apply pressure the TCM will command of the TRIM valves via the trim solenoids in the tuning. After a shift is complete though, the clutch packs will have the same amount of pressure to them though(wether it's 125 PSI MAX in a stock ALLISON, or line pressure with a TRANSGO kit installed).
The big thing I think most get hung up on comparing the ALLISON to other trannies like a 400 or 700, is those trannies have safety nets designed into them whereas the ALLISON doesn't. In a 700R4 style trans for example, the 1-2 shift is simply applying the 2-4 band, so there is ZERO chance of a tie up. So if you want a firm snappy shift, just make it fill the 2nd servo quicker. Or the 2-3 shift where the fluid going into apply the 3-4 direct clutch pack also forces the 1-R clutch pack off to stop any chance of tie ups. The ALLISON has NO safeties built in other than TAPS. During a shift it must select the correct shift valve positions via the shift solenoids, release one of the applied clutch packs while simultaneously applying the next clutch pack via the trim solenoids, and do so in a timely fashion as to prevent it from going to neutral, but also not do it so quickly that 3 clutch packs are on at the same time engaging the mother of all trans brakes. There are no safeties in the shift process other than the learned TAPS and shift timing to allow the TCM to know when and how to do what.
For those who don't understand why adaptive learning is so important, they need to read the ALLISON PRINCIPLES OF OPERATIONS manual. It goes into great detail describing each shift, what takes palce, all of the checks the TCM does during a shift, and what it has to do after a shift to prepare for the next shift. It would boggle your mind to see just how many stes the TCM must do for each shift.