Here is what the Chevrolet.com site says about DEF freezing (apparenlty they were wrong):
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Q. Will DEF freeze?
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Yes, DEF will freeze—at approximately 12ºF. If DEF is frozen, the vehicle will start as it always has. As soon as the vehicle is started, the DEF tank and lines are electrically heated to ensure adequate DEF delivery in cold weather. The DEF thaws with no degradation. Remember, since this system was designed to operate in cold weather, there is no impact on cold-weather engine operation.
Q. Does DEF expand when it freezes and if so, how does it impact the tank?
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Yes, DEF expands when it freezes. The vehicle’s DEF tank and all DEF packaging is designed to accommodate any expansion that may result from being frozen.
Q. C an a freeze-point improver be added to the DEF to keep it from freezing?
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No, doing so would alter the DEF mixture balance potentially triggering an “EXHAUST FLUID QUALITY POOR” DIC message.
Here is what Fleetguard says about DEF freezing.
Here is what Fleetguard says about DEF freezing.
Q. What is the freeze point of DEF?
A. A 32.5% solution of DEF will begin to crystallize and freeze at 11 deg F. At 32.5%, both the urea and water will freeze at the same rate, ensuring that the fluid does not become diluted or over concentrated.
Q. With a freezing temperature of 11 deg F or -11 deg C, what happens to the
operation of the vehicle if the DEF freezes?
A. If the DEF freezes, it will not inhibit the operator from starting the vehicle. DEF
thaws quickly once you start the vehicle.A. A 32.5% solution of DEF will begin to crystallize and freeze at 11 deg F. At 32.5%, both the urea and water will freeze at the same rate, ensuring that the fluid does not become diluted or over concentrated.
Q. With a freezing temperature of 11 deg F or -11 deg C, what happens to the
operation of the vehicle if the DEF freezes?
A. If the DEF freezes, it will not inhibit the operator from starting the vehicle. DEF